Expt CVD1 : Constant Volume Depletion Peng-Robinson (3-Parm) on ZI with PR corr. Lohrenz-Bray-Clark Viscosity Correlation Density units are KG/M3 Specific volume units are M3/KG-ML Viscosity units are CPOISE Surface Tension units are DYNES/CM Specified temperature Deg C 81.0000 ------------------- ------------ ------------ ------------ ------------ Rel Volume Vap Mole Frn Liq Density Vap Density Pressure Inserted ------------ ------------ ------------ ------------ BARSA Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 1.0000 183.9396 214.299 - Psat 1.0000 552.0655 179.9809 200.000 0.0047 0.9953 559.1313 167.4142 180.000 0.0100 0.9897 569.4055 149.5956 160.000 0.0138 0.9846 580.6077 131.5227 140.000 0.0165 0.9799 593.0221 113.3727 120.000 0.0181 0.9757 606.6385 95.3992 100.000 0.0188 0.9717 621.2995 77.8416 80.000 0.0186 0.9677 636.8316 60.8872 60.000 0.0178 0.9632 653.0826 44.6655 42.000 0.0165 0.9567 668.2082 30.7525 22.000 0.0144 0.9505 685.5364 16.0369 2.000 0.0082 0.9583 701.7993 1.6858 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ Liq Z-Fac Vap Z-Fac Surf Tension Pressure Inserted ------------ ------------ ------------ BARSA Point Calculated Calculated Calculated ------------------- ------------ ------------ ------------ 220.000 0.8716 214.299 - Psat 0.8535 0.8677 0.8283 200.000 0.8107 0.8619 1.0820 180.000 0.7475 0.8569 1.5505 160.000 0.6820 0.8560 2.1877 140.000 0.6148 0.8595 3.0327 120.000 0.5457 0.8674 4.1176 100.000 0.4739 0.8794 5.4632 80.000 0.3982 0.8954 7.0755 60.000 0.3167 0.9152 8.9378 42.000 0.2365 0.9360 10.7835 22.000 0.1364 0.9626 12.8731 2.000 0.0158 0.9949 13.3298 ------------------- ------------ ------------ ------------ ------------------- ------------------------- ------------ ------------ Liq Sat Liq Visc Vap Visc Pressure Inserted ------------------------- ------------ ------------ BARSA Point Observed Calculated Calculated Calculated ------------------- ------------------------- ------------ ------------ 220.000 0.0226 214.299 - Psat 0.1166 0.0222 200.000 0.0040 0.0047 0.1212 0.0210 180.000 0.0081 0.0100 0.1283 0.0195 160.000 0.0129 0.0138 0.1368 0.0181 140.000 0.0163 0.0165 0.1475 0.0168 120.000 0.0182 0.0181 0.1607 0.0157 100.000 0.0195 0.0188 0.1769 0.0148 80.000 0.0190 0.0186 0.1966 0.0141 60.000 0.0181 0.0178 0.2203 0.0135 42.000 0.0168 0.0165 0.2452 0.0131 22.000 0.0149 0.0144 0.2767 0.0127 2.000 0.0124 0.0082 0.2991 0.0120 ------------------- ------------------------- ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Moles Extrac 2-Ph Z-Fac Liq Mol Vol Vap Mol Vol Pressure Inserted ------------ ------------ ------------ ------------ BARSA Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 0.8716 0.1167 214.299 - Psat 0.8677 0.1173 0.1192 200.000 0.0601 0.8616 0.1193 0.1269 180.000 0.1482 0.8556 0.1223 0.1402 160.000 0.2405 0.8530 0.1255 0.1575 140.000 0.3362 0.8539 0.1293 0.1808 120.000 0.4338 0.8582 0.1339 0.2128 100.000 0.5322 0.8655 0.1395 0.2589 80.000 0.6298 0.8751 0.1465 0.3296 60.000 0.7256 0.8854 0.1554 0.4491 42.000 0.8094 0.8924 0.1658 0.6562 22.000 0.8994 0.8852 0.1826 1.2884 2.000 0.9877 0.6601 0.2324 14.6468 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(1 ,CO2 ) Com(2 ,N2 ) Com(3 ,C1 ) Com(4 ,C2 ) K-Values Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 1.0000 1.0000 1.0000 1.0000 214.299 - Psat 1.1352 2.4328 1.6389 0.9483 200.000 1.1637 2.6226 1.7162 0.9537 180.000 1.2138 2.9445 1.8460 0.9661 160.000 1.2801 3.3579 2.0113 0.9868 140.000 1.3705 3.9035 2.2286 1.0205 120.000 1.4969 4.6454 2.5236 1.0745 100.000 1.6811 5.6962 2.9415 1.1614 80.000 1.9662 7.2807 3.5733 1.3058 60.000 2.4525 9.9227 4.6312 1.5647 42.000 3.2992 14.4407 6.4497 2.0303 22.000 5.8912 28.0736 11.9731 3.4875 2.000 60.5220 310.4205 128.4836 34.9460 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(5 ,C3 ) Com(6 ,IC4 ) Com(7 ,NC4 ) Com(8 ,FRC1) K-Values Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 1.0000 1.0000 1.0000 1.0000 214.299 - Psat 0.6422 0.4885 0.4335 0.3092 200.000 0.6270 0.4668 0.4109 0.2865 180.000 0.6074 0.4379 0.3810 0.2567 160.000 0.5911 0.4113 0.3534 0.2297 140.000 0.5802 0.3885 0.3294 0.2060 120.000 0.5779 0.3711 0.3105 0.1865 100.000 0.5891 0.3620 0.2987 0.1720 80.000 0.6234 0.3656 0.2975 0.1642 60.000 0.7019 0.3923 0.3148 0.1664 42.000 0.8603 0.4597 0.3645 0.1853 22.000 1.3864 0.7036 0.5509 0.2682 2.000 13.0616 6.2775 4.8683 2.2782 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(9 ,FRC2) Com(10,FRC3) Com(11,FRC4) Com(12,FRC5) K-Values Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 1.0000 1.0000 1.0000 1.0000 214.299 - Psat 0.2312 0.1359 0.0597 0.0158 200.000 0.2095 0.1183 0.0487 0.0116 180.000 0.1817 0.0965 0.0361 0.0073 160.000 0.1568 0.0778 0.0262 0.0045 140.000 0.1351 0.0624 0.0187 0.0026 120.000 0.1172 0.0500 0.0132 0.0015 100.000 0.1034 0.0405 0.0093 0.0008 80.000 0.0941 0.0337 0.0067 0.0005 60.000 0.0908 0.0297 0.0051 0.0003 42.000 0.0966 0.0290 0.0043 0.0002 22.000 0.1327 0.0360 0.0046 0.0001 2.000 1.0663 0.2596 0.0273 0.0006 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(1 ,CO2 ) Com(2 ,N2 ) Com(3 ,C1 ) Com(4 ,C2 ) Fluid, Z Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 0.8550 1.7850 85.8000 4.3050 214.299 - Psat 0.8550 1.7850 85.8000 4.3050 200.000 0.8550 1.7847 85.7891 4.3051 180.000 0.8548 1.7834 85.7469 4.3052 160.000 0.8545 1.7810 85.6654 4.3053 140.000 0.8538 1.7771 85.5275 4.3051 120.000 0.8526 1.7712 85.3078 4.3038 100.000 0.8505 1.7623 84.9664 4.3003 80.000 0.8469 1.7489 84.4319 4.2916 60.000 0.8403 1.7280 83.5551 4.2714 42.000 0.8288 1.6961 82.1584 4.2292 22.000 0.7970 1.6201 78.6685 4.0908 2.000 0.5517 1.1143 54.2258 2.8476 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(5 ,C3 ) Com(6 ,IC4 ) Com(7 ,NC4 ) Com(8 ,FRC1) Fluid, Z Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 2.5050 0.6650 0.5500 0.6532 214.299 - Psat 2.5050 0.6650 0.5500 0.6532 200.000 2.5055 0.6652 0.5502 0.6537 180.000 2.5072 0.6661 0.5512 0.6556 160.000 2.5104 0.6679 0.5530 0.6596 140.000 2.5156 0.6708 0.5561 0.6664 120.000 2.5231 0.6754 0.5611 0.6774 100.000 2.5334 0.6821 0.5684 0.6945 80.000 2.5462 0.6917 0.5790 0.7204 60.000 2.5599 0.7047 0.5940 0.7595 42.000 2.5678 0.7198 0.6124 0.8130 22.000 2.5357 0.7329 0.6336 0.8995 2.000 1.8046 0.5412 0.4773 0.7443 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(9 ,FRC2) Com(10,FRC3) Com(11,FRC4) Com(12,FRC5) Fluid, Z Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 1.1364 1.0093 0.5578 0.1783 214.299 - Psat 1.1364 1.0093 0.5578 0.1783 200.000 1.1377 1.0115 0.5609 0.1815 180.000 1.1429 1.0208 0.5734 0.1925 160.000 1.1535 1.0399 0.5988 0.2106 140.000 1.1724 1.0746 0.6431 0.2375 120.000 1.2037 1.1332 0.7146 0.2761 100.000 1.2536 1.2288 0.8274 0.3324 80.000 1.3321 1.3847 1.0078 0.4188 60.000 1.4574 1.6488 1.3167 0.5640 42.000 1.6423 2.0783 1.8431 0.8109 22.000 2.0011 3.1366 3.3507 1.5335 2.000 1.9636 5.5364 17.7764 12.4167 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ Molar Distributions Total Fluid, Z Inserted ------------ Point Calculated ------------------- ------------ 220.000 100.0000 214.299 - Psat 100.0000 200.000 100.0000 180.000 100.0000 160.000 100.0000 140.000 100.0000 120.000 100.0000 100.000 100.0000 80.000 100.0000 60.000 100.0000 42.000 100.0000 22.000 100.0000 2.000 100.0000 ------------------- ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(1 ,CO2 ) Com(2 ,N2 ) Com(3 ,C1 ) Com(4 ,C2 ) Liquid, X Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 214.299 - Psat 0.7532 0.7337 52.3519 4.5398 200.000 0.7352 0.6826 50.0920 4.5129 180.000 0.7057 0.6103 46.6941 4.4546 160.000 0.6700 0.5369 42.9647 4.3619 140.000 0.6269 0.4632 38.8681 4.2205 120.000 0.5750 0.3900 34.3961 4.0132 100.000 0.5130 0.3184 29.5534 3.7203 80.000 0.4396 0.2490 24.3452 3.3184 60.000 0.3530 0.1823 18.7732 2.7797 42.000 0.2626 0.1247 13.4474 2.1511 22.000 0.1467 0.0634 7.1881 1.2571 2.000 0.0137 0.0054 0.6387 0.1220 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(5 ,C3 ) Com(6 ,IC4 ) Com(7 ,NC4 ) Com(8 ,FRC1) Liquid, X Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 214.299 - Psat 3.9006 1.3614 1.2687 2.1124 200.000 3.9842 1.4170 1.3294 2.2535 180.000 4.0975 1.4993 1.4205 2.4720 160.000 4.1967 1.5845 1.5168 2.7137 140.000 4.2648 1.6667 1.6129 2.9715 120.000 4.2773 1.7360 1.6994 3.2307 100.000 4.2000 1.7771 1.7613 3.4652 80.000 3.9862 1.7665 1.7748 3.6316 60.000 3.5718 1.6682 1.7027 3.6549 42.000 2.9547 1.4588 1.5151 3.4432 22.000 1.8780 1.0021 1.0685 2.6703 2.000 0.2019 0.1210 0.1346 0.4043 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(9 ,FRC2) Com(10,FRC3) Com(11,FRC4) Com(12,FRC5) Liquid, X Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 214.299 - Psat 4.9146 7.4261 9.3510 11.2864 200.000 5.3280 8.2427 10.4825 10.9398 180.000 5.9838 9.5609 12.1820 10.3194 160.000 6.7325 11.0885 13.9181 9.7157 140.000 7.5647 12.8120 15.6153 9.3135 120.000 8.4535 14.7061 17.3029 9.2199 100.000 9.3480 16.7439 19.1203 9.4791 80.000 10.1583 18.9049 21.2913 10.1343 60.000 10.7189 21.1656 24.1418 11.2878 42.000 10.7372 23.2077 27.7376 12.9599 22.000 9.3496 24.8134 34.2298 16.3330 2.000 1.8815 10.7976 49.4027 36.2766 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ Molar Distributions Total Liquid, X Inserted ------------ Point Calculated ------------------- ------------ 220.000 214.299 - Psat 100.0000 200.000 100.0000 180.000 100.0000 160.000 100.0000 140.000 100.0000 120.000 100.0000 100.000 100.0000 80.000 100.0000 60.000 100.0000 42.000 100.0000 22.000 100.0000 2.000 100.0000 ------------------- ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(1 ,CO2 ) Com(2 ,N2 ) Com(3 ,C1 ) Com(4 ,C2 ) Vapour, Y Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 0.8550 1.7850 85.8000 4.3050 214.299 - Psat 0.8550 1.7850 85.8000 4.3050 200.000 0.8556 1.7903 85.9701 4.3040 180.000 0.8565 1.7969 86.1974 4.3035 160.000 0.8577 1.8029 86.4170 4.3043 140.000 0.8591 1.8080 86.6230 4.3071 120.000 0.8607 1.8117 86.8008 4.3124 100.000 0.8625 1.8135 86.9320 4.3208 80.000 0.8642 1.8129 86.9925 4.3331 60.000 0.8658 1.8089 86.9431 4.3494 42.000 0.8665 1.8007 86.7313 4.3675 22.000 0.8643 1.7811 86.0636 4.3840 2.000 0.8311 1.6903 82.0616 4.2634 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(5 ,C3 ) Com(6 ,IC4 ) Com(7 ,NC4 ) Com(8 ,FRC1) Vapour, Y Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 2.5050 0.6650 0.5500 0.6532 214.299 - Psat 2.5050 0.6650 0.5500 0.6532 200.000 2.4980 0.6614 0.5463 0.6456 180.000 2.4888 0.6565 0.5411 0.6347 160.000 2.4807 0.6517 0.5361 0.6234 140.000 2.4745 0.6474 0.5313 0.6122 120.000 2.4717 0.6443 0.5277 0.6025 100.000 2.4743 0.6433 0.5261 0.5962 80.000 2.4848 0.6459 0.5281 0.5963 60.000 2.5070 0.6544 0.5361 0.6081 42.000 2.5420 0.6706 0.5523 0.6380 22.000 2.6037 0.7051 0.5886 0.7163 2.000 2.6371 0.7595 0.6553 0.9210 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ ------------ ------------ ------------ Molar Distributions Com(9 ,FRC2) Com(10,FRC3) Com(11,FRC4) Com(12,FRC5) Vapour, Y Inserted ------------ ------------ ------------ ------------ Point Calculated Calculated Calculated Calculated ------------------- ------------ ------------ ------------ ------------ 220.000 1.1364 1.0093 0.5578 0.1783 214.299 - Psat 1.1364 1.0093 0.5578 0.1783 200.000 1.1164 0.9749 0.5106 0.1270 180.000 1.0870 0.9223 0.4395 0.0757 160.000 1.0553 0.8631 0.3644 0.0433 140.000 1.0224 0.7991 0.2916 0.0244 120.000 0.9911 0.7352 0.2282 0.0138 100.000 0.9665 0.6785 0.1785 0.0080 80.000 0.9560 0.6380 0.1434 0.0048 60.000 0.9731 0.6281 0.1230 0.0031 42.000 1.0370 0.6721 0.1197 0.0024 22.000 1.2409 0.8940 0.1561 0.0024 2.000 2.0063 2.8035 1.3482 0.0227 ------------------- ------------ ------------ ------------ ------------ ------------------- ------------ Molar Distributions Total Vapour, Y Inserted ------------ Point Calculated ------------------- ------------ 220.000 100.0000 214.299 - Psat 100.0000 200.000 100.0000 180.000 100.0000 160.000 100.0000 140.000 100.0000 120.000 100.0000 100.000 100.0000 80.000 100.0000 60.000 100.0000 42.000 100.0000 22.000 100.0000 2.000 100.0000 ------------------- ------------